Mechanical and electrochemical properties of Nb2O5, Nb2O5: Cu and graphene layers deposited on titanium alloy (Ti6Al4V)
PBN-AR
Instytucja
Wydział Fizyki (Politechnika Warszawska)
Informacje podstawowe
Główny język publikacji
angielski
Czasopismo
Surface Coatings Technology
ISSN
0257-8972
EISSN
Wydawca
Elsevier
DOI
Rok publikacji
2015
Numer zeszytu
Strony od-do
92–99
Numer tomu
271
Identyfikator DOI
Liczba arkuszy
0.5
Autorzy
(liczba autorów: 8)
Pozostali autorzy
+ 6
Słowa kluczowe
en
Alloys; Coatings; Copper; Corrosion; Corrosion resistance; Film preparation; Graphene; Hardness; Hybrid systems; Magnetron sputtering; Mechanical properties; Medical applications; Monolayers; Nanoindentation; Niobium; Niobium oxide; Thin films; Titanium, Biomedical applications; Corrosion property; Corrosive environment; Engineering applications; Magnetron sputtering method; Mechanical and corrosion properties; Structural characteristics; Ti6al4v titanium alloys, Titanium alloys
Streszczenia
Język
en
Treść
In this paper the comparative studies on structural, mechanical and corrosion properties of Nb2O5/Ti, Nb2O5:Cu/Ti-Al-V and graphene/Ti alloy systems have been investigated. The pure nioba and nioba with copper addition were deposited on Ti6Al4V titanium alloy surface by magnetron sputtering method. Graphene monolayer was transferred on titanium alloy substrate using "PMMA-mediated" method. The structural characteristics of obtained thin films were examined by using of Raman spectroscopy, SEM and AFM measurement. The mechanical properties i.e.: nanohardness, were performed by using nanoindenter. Corrosion properties of the coatings were determined by analysis of the voltammetric curves.The deposited Nb2O5 and Nb2O5:Cu coatings were crack free and exhibited good adherence to the substrate, no discontinuities of the thin films were observed and the surface morphology was homogeneous. Graphene transferred on titanium alloy surface was a single layer without defects.The hardness of pure niobium pentoxide was ca. 8.64GPa, nioba with copper addition was equal 7.79GPa and graphene depositied on titanium alloy surface was equal 5.63GPa. As obtained results show, graphene monolayer has no effect on surface hardness of titanium alloy. However, sample Ti6Al4V coated with a single layer of graphene is characterized by the best corrosion resistance. Similar results were obtained for the sample covered by 210nm thick Nb2O5:Cu thin film.It seems, that the combined advantages of these three layers, i.e., niobium pentoxide, niobium with copper addition and a monolayer of graphene, in the hybrid multilayer system can greatly improve the mechanical and corrosion properties of the titanium alloy surface. This hybrid system can be used in the future, as protection coatings for Ti alloy, in biomedical application and in other application, where Ti alloy works in an aggressive corrosive environment and in engineering applications where friction is involved.
Inne
System-identifier
WUTda394c5eb1b048e990a73a55a6d610d9
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