Aggregation behavior of dicephalic di-N-oxide surfactants in aqueous solution: experimental and computational approaches
PBN-AR
Instytucja
Wydział Chemiczny (Politechnika Wrocławska)
Informacje podstawowe
Główny język publikacji
eng
Czasopismo
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN
0927-7757
EISSN
Wydawca
DOI
URL
Rok publikacji
2014
Numer zeszytu
Strony od-do
34-41
Numer tomu
vol. 442
Identyfikator DOI
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Autorzy
(liczba autorów: 5)
Pozostali autorzy
+ 3
Słowa kluczowe
pol
N-tlenki
micelizacja
elektronowy rezonans paramagnetyczny (EPR)
Streszczenia
Język
eng
Treść
A series of dicephalic-type 1,1-bis{[3-(N,N-dimethylamino) ethyl]amido}alkane-di-N-oxide surfactants were synthesized and their aggregation behavior in an aqueous environment was described, both experimentally and theoretically. Surface tension and electron paramagnetic resonance (EPR) spectroscopy were applied to monitor the micellization behavior of the studied dicephalic surfactants in aqueous solutions. In the EPR experiments two nitroxide spin probes (5- and 16-doxylstearic acids) were used whereby not only the critical micelle concentrations could be determined, but also the microenvironment of the formed aggregates could be investigated as a function of temperature and surfactant concentration. Furthermore, the size of the micellar aggregates and the polydispersity indexes of the micellar solutions were established by dynamic light scattering (DLS). The structures of the formed aggregates, defined by the critical packing parameter, were predicted using the QSAR approach. The hydrodynamic radii, micellar volumes and aggregation numbers were computed with the long range corrected B3LYP hybrid functional (CAM-B3LYP). In order to put the results obtained for the dicephalics into perspective the experiments and computations were performed for the standard 2-(dodecanoylamino)ethyldimethylamine-N-oxide.
Inne
System-identifier
000191533
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