Synthesis and characterization of noble metal–titania core–shell nanostructures with tunable shell thickness
PBN-AR
Instytucja
Instytut Optoelektroniki (Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego)
Informacje podstawowe
Główny język publikacji
en
Czasopismo
Beilstein Journal of Nanotechnology (35pkt w roku publikacji)
ISSN
2190-4286
EISSN
Wydawca
DOI
URL
Rok publikacji
2017
Numer zeszytu
Strony od-do
2083-2093
Numer tomu
8
Identyfikator DOI
Liczba arkuszy
10.00
Słowa kluczowe
en
Ag@TiO2; Au@TiO2; core–shell nanostructures; titania coating; titanium dioxide; tunable resistive pulse sensing
Streszczenia
Język
en
Treść
Core–shell nanostructures have found applications in many fields, including surface enhanced spectroscopy, catalysis and solar cells. Titania-coated noble metal nanoparticles, which combine the surface plasmon resonance properties of the core and the photoactivity of the shell, have great potential for these applications. However, the controllable synthesis of such nanostructures remains a challenge due to the high reactivity of titania precursors. Hence, a simple titania coating method that would allow better control over the shell formation is desired. A sol–gel based titania coating method, which allows control over the shell thickness, was developed and applied to the synthesis of Ag@TiO2 and Au@TiO2 with various shell thicknesses. The morphology of the synthesized structures was investigated using scanning electron microscopy (SEM). Their sizes and shell thicknesses were determined using tunable resistive pulse sensing (TRPS) technique. The optical properties of the synthesized structures were characterized using UV–vis spectroscopy. Ag@TiO2 and Au@TiO2 structures with shell thickness in the range of ≈40–70 nm and 90 nm, for the Ag and Au nanostructures respectively, were prepared using a method we developed and adapted, consisting of a change in the titania precursor concentration. The synthesized nanostructures exhibited significant absorption in the UV–vis range. The TRPS technique was shown to be a very useful tool for the characterization of metal–metal oxide core–shell nanostructures.
Cechy publikacji
ORIGINAL_ARTICLE
Inne
System-identifier
836686
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