Dynamic glass transition and electrical conductivity behavior dominated by proton hopping mechanism studied in the family of hyperbranched bis-MPA polyesters
PBN-AR
Instytucja
Centrum Nanobiomedyczne (Uniwersytet im. Adama Mickiewicza w Poznaniu)
Informacje podstawowe
Główny język publikacji
en
Czasopismo
MACROMOLECULES
ISSN
0024-9297
EISSN
Wydawca
AMER CHEMICAL SOC
DOI
URL
Rok publikacji
2014
Numer zeszytu
16
Strony od-do
5798-5807
Numer tomu
47
Identyfikator DOI
Liczba arkuszy
Streszczenia
Język
en
Treść
Dielectric and infrared spectroscopies were employed to study inter- and intramolecular glass-transition dynamics in the series of hyperbranched polyesters of the second, third, and fourth generations. Our study shows that conductivity relaxation becomes increasingly faster than structural relaxation as the glass transition temperature Tg is approached, signifying decoupling between translational motions of charges and reorientation of molecules. Depending on the polymer’s generation conductivity relaxation times can be up to few orders of magnitude faster than structural dynamics. Because of extensive hydrogen bonding network, the most significant contribution to the total ionic conductivity comes from proton transfer along hydrogen bonds. Decoupling phenomenon was accompanied by narrowing the dispersion of the conductivity relaxation with decreasing temperature that reaches almost exponential decay in the glassy state. Finally, by analyzing the absorption spectra in terms of integral intensity, we have demonstrated significant role of H-bonded moieties in the course of vitrification of investigated materials
Cechy publikacji
discipline:Chemia
discipline:Fizyka
discipline:Chemistry
discipline:Physics
Original article
Original article presents the results of original research or experiment.
Oryginalny artykuł naukowy
Oryginalny artykuł naukowy przedstawia rezultaty oryginalnych badań naukowych lub eksperymentu.
Inne
System-identifier
PBN-R:611249
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